Automated HPLC Separation of Endohedral Metallofullerene Sc@C2n and Y@C2n Fractions
نویسندگان
چکیده
منابع مشابه
Endohedral Metallofullerene in Gas Phase
Mass-spectroscopic experiments related to the endohedral metallofullerene are reviewed. Generation techniques of gas phase clusters, FT-ICR mass spectroscopy experiments, and ion mobility experiments are overviewed. Based on those experimental results, the formation mechanism of endohedral metallofullerene is discussed with classical molecular dynamics simulation results. Finally, exotic predic...
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In terms of density functional theory combined with statistic mechanics computations, we investigated a dimetallic sulfide endohedral fullerene Sc2S@C76 which has been synthesized without any characterization in experiments. Our theoretical study reveals that Sc2S@Td(19151)-C76 which satisfies the isolated-pentagon rule (IPR) possesses the lowest energy, followed by three non-IPR structures (Sc...
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Understanding the formation mechanism of SWNTs and endohedral metallofullerene is very interesting and also very important for the large-scale generation and controlled generation of various possible structures, such as different cage size and different metal species for metallofullerene and various radii and chiralities of SWNTs. Both endohedral metallofullerene and SWNTs are usually generated...
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ژورنال
عنوان ژورنال: Analytical Chemistry
سال: 1994
ISSN: 0003-2700,1520-6882
DOI: 10.1021/ac00089a013